1,3-Diprop-2-ynyl-1H-imidazol-3-ium bromide

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1,3-Diprop-2-ynyl-1H-imidazol-3-ium bromide

In the title salt, C(9)H(9)N(2) (+)·Br(-), the ethynyl groups are nearly anti-parallel to each other [the angle between the two ethynyl groups is179.7 (2)°]. No classical hydrogen bonds or π-π inter-actions are observed. The mol-ecules are linked by C-H⋯Br hydrogen bonds. The bromide anions are involved in inter-actions with three H atoms.

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3-(2-Bromo­benz­yl)-1-methyl-1H-imidazol-3-ium bromide

In the title compound, C(11)H(12)BrN(2) (+)·Br(-), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical inter-molecular C-H⋯Br hydrogen bonds and inversion-related mol-ecules are linked through π-π inter-actions between the imidazole ring systems [centroid-centroid distance = 3.472 (6) Å].

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4,5-Dibromo-1,2-dimethyl-1H-imidazol-3-ium bromide

In the title salt, C(5)H(7)Br(2)N(2) (+)·Br(-), the cation and anion are connected by an N-H⋯Br hydrogen bond. In the crystal, there are inter-calated layers parallel to (10-2) in which bromide ions are located between the cations. Weak inter-molecular C-H⋯Br hydrogen bonds are also observed.

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1-[6-(Hydroxy­meth­yl)-2-pyrid­yl]-3-(2,4,6-trimethyl­benz­yl)-1H-imidazol-3-ium bromide

In the title compound, C(19)H(22)N(3)O(+)·Br(-), the imidazole ring is approximately coplanar with the pyridine ring [dihedral angle = 0.88 (13)°] and nearly perpendicular to the benzene ring [dihedral angle = 81.70 (13)°]. O-H⋯Br and C-H⋯Br hydrogen bonding helps to stabilize the crystal structure.

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Bis[2-(1H-imidazol-2-yl-κN 3)-1H-imidazol-3-ium]silver(I) trinitrate

The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2'-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N-Ag-N = 177.01 (17)°]. The crystal structure displays N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808010726